Double-component modified molecular sieve with improved hydrothermal stability and production method thereof

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United States of America Patent

PATENT NO 9895686
SERIAL NO

13505219

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A method for producing double-component modified molecular sieve comprises adding molecular sieve to an aqueous solution containing phosphorus to form a mixture, allowing the mixture to react at pH of 1-10, temperature of 70-200° C. and pressure of 0.2-1.2 MPa for 10-200 min, and then filtering, drying and baking the resultant to obtain phosphorus-modified molecular sieve, and then adding the phosphorus-modified molecular sieve to an aqueous solution containing silver ions, allowing the phosphorus-modified molecular sieve to react with silver ions at 0-100° C. in dark condition for 30-150 min, and then filtering, drying and baking. The obtained double-component modified molecular sieve contains 88-99 wt % molecular sieve with a ratio of silica to alumina between 15 and 60, 0.5-10 wt % phosphorus (based on oxides) and 0.01-2 wt % silver (based on oxides), all based on dry matter. A catalyst produced from the double-component modified molecular sieve has improved hydrothermal stability and microactivity.

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Patent OwnerAddress
PETRO CHINE COMPANY LIMITEDNO 9 DONGZHIMEN NORTH STREET DONGCHENG DISTRICT BEIJING 100007

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Duan, Hongchang Lanzhou, CN 10 17
Gao, Xionghou Lanzhou, CN 11 17
Ji, Dong Lanzhou, CN 18 89
Li, Di Lanzhou, CN 99 1029
Ma, Yanqing Lanzhou, CN 2 1
Su, Yi Lanzhou, CN 108 1505
Sun, Yanbo Lanzhou, CN 5 11
Tan, ZhengGuo Lanzhou, CN 11 26
Tang, Zhicheng Lanzhou, CN 9 61
Wang, Yi Lanzhou, CN 1349 14754
Zhang, Haitao Lanzhou, CN 173 1178

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