Process for the gas-phase polymerization of ethylene or ethylene mixtures

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United States of America Patent

PATENT NO 9873754
SERIAL NO

14891506

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Abstract

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A process for the gas-phase polymerization of ethylene or a mixture of ethylene and one or more 1 olefins in the presence of a polymerization catalyst system comprising the steps

    a) feeding a solid catalyst component, which was obtained by contacting at least a magnesium compound and a titanium compound, to a continuously operated apparatus and contacting the solid catalyst component with an aluminum alkyl compound at a temperature of from 0° C. to 70° C. in a way that the mean residence time of the solid catalyst component in contact with the aluminum alkyl compound is from 5 to 300 minutes;b) transferring the catalyst component formed in step a) into another continuously operated apparatus and prepolymerizing it with ethylene or a mixture of ethylene and one or more 1 olefins in suspension at a temperature of from 10° C. to 80° forming polymer in an amount of from 0.2 to 25 g polymer/g of solid catalyst component in a way that the mean residence time of the solid catalyst component in the apparatus is from 5 minutes to 3 hours; andc) transferring the prepolymerized catalyst component formed in step b) into a gas-phase polymerization reactor and polymerizing ethylene or a mixture of ethylene and one or more 1 olefins in the presence of the prepolymerized catalyst component at temperatures of from 40° C. to 120° C. and pressures of from 0.1 to 10 MPa.

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Patent Owner(s)

Patent OwnerAddress
BASELL POLYOLEFINE GMBHGERMANY WESSEL NING

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Baita, Pietro Ferrara, IT 34 158
Marturano, Lorella Ferrara, IT 11 6
Mazzucco, Antonio Ferrara, IT 30 46
Mei, Gabriele Ferrara, IT 41 251
Meier, Gerhardus Frankfurt/M, DE 85 351
Pica, Roberta Ferrara, IT 20 22
Schueller, Ulf Frankfurt/M, DE 32 99

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