Modular assembly of metal-organic super-containers incorporating calixarenes
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United States of America Patent
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Jan 16, 2018
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Apr 15, 2013
filing date -
Apr 13, 2012
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Abstract
A new strategy to design container molecules is presented. Sulfonylcalix[4]arenes, which are synthetic macrocyclic containers, are used as building blocks that are combined with various metal ions and tricarboxylate ligands to construct metal-organic ‘super-containers’ (MOSCs). These MOSCs possess both endo and exo cavities and thus mimic the structure of viruses. The synthesis of MOSCs is highly modular, robust, and predictable.
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