Polymerization of diene monomers

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United States of America Patent

PATENT NO 9862789
SERIAL NO

14901846

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Abstract

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A free radical or controlled radical polymerization process of atom or group transfer radical polymerization. The process comprises radically polymerizing one or more radically (co)polymerizable monomers in the presence of a polymerization system. The one or more radically (co)polymerizable monomers comprise at least one or more radically (co)polymerizable diene monomers. The polymerization system comprises: an initiator having one or more radically transferable atoms or groups; a transition metal-ligand complex catalyst, wherein the ligand comprises any C-, N-, O-, P- or S-containing ligand which coordinates with the transition metal; an optional reducing agent capable of regenerating the lower oxidation state of the transition metal catalyst; and an optional organic solvent or water capable of solubilizing the transition metal-ligand complex catalyst. (Co)polymers produced by the free radical or controlled radical polymerization process of atom or group transfer radical polymerization.

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Patent Owner(s)

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UNIVERSITY OF CONNECTICUT400 FARMINGTON AVENUE FARMINGTON CT 06032

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Asandei, Alexandru D Vernon, US 4 15

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