High nickel cathode material having low soluble base content
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United States of America Patent
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Jul 4, 2017
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N/A
app pub date -
Jan 31, 2012
filing date -
Feb 7, 2011
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Abstract
The invention relates to cathode materials for Li-ion batteries in the quaternary phase diagram Li[Li1/3Mn2/3]O2—LiMn1/2Ni1/2O2—LiNiO2—LiCoO2, and having a high nickel content. Also a method to manufacture these materials is disclosed. The cathode material has a general formula Lia ((Niz(Ni1/2Mn1/2)yCox)1−kAk)2−aO2, wherein x+y+z=1, 0.1≦x≦0.4, 0.36≦z≦0.50, A is a dopant, 0≦k≦0.1, and 0.95≦a≦1.05, and having a soluble base content (SBC) within 10% of the equilibrium soluble base content.
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