Low formaldehyde vinyl ester/ethylene emulsion copolymers

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United States of America Patent

PATENT NO 9567261
APP PUB NO 20150141553A1
SERIAL NO

14396506

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Abstract

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A vinyl ester/ethylene copolymer is prepared by emulsion copolymerization of a monomer mixture comprising at least one vinyl ester, ethylene, a stabilizing system comprising polyvinyl alcohol and a free radical redox polymerization initiator system comprising i-butyl hydroperoxide as an oxidizing agent and at least one of a sulfuric acid-based compound and erythorbic acid or a salt thereof as a reducing agent. The monomer mixture comprises from 70 wt % to 95 wt % of said at least one vinyl ester and from 5 wt % to 30 wt % of ethylene based on the total weight of monomers in said mixture and the copolymer has a formaldehyde content of less than 5.0 ppmw as determined by ISO-15173.

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Patent Owner(s)

Patent OwnerAddress
CELANESE SALES GERMANY GMBH65843 SULZBACH TAUNUS

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
McLennan, Alistair Koenigstein, DE 8 6
Van, Boxtel Hendrikus C M Frankfurt am Main, DE 1 0

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