Reductive dehydroxylation of vicinal polyols to olefins using an iodine-based catalyst having enhanced solubility
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United States of America Patent
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Nov 22, 2016
Grant Date -
Dec 25, 2014
app pub date -
Dec 5, 2012
filing date -
Dec 15, 2011
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Abstract
Olefins may be produced by the reductive dehydroxylation of vicinal polyols and/or their respective esters, in an aqueous reaction medium, under a hydrogen atmosphere, under suitable conditions, and in the presence of a halogen-based, preferably iodine-based, catalyst, wherein a solubility enhancing agent is employed to increase the solubility of the iodine-based catalyst in the aqueous reaction medium.
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