Conjugated microporous macromolecule catalyst complexed with cobalt, preparation and use thereof

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United States of America Patent

PATENT NO 9249120
SERIAL NO

14114663

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Abstract

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Disclosed are a type of catalyst which can catalyze the ring-addition reaction of CO2 and an alkylene oxide at 0˜180° C. under 0.1˜8.0 MPa to produce a corresponding cyclic carbonate, and the preparation thereof. The catalyst is a conjugated microporous macromolecule polymer complexed with cobalt, chromium, zinc, copper or aluminum, and by using the macromolecule catalysts complexed with different metals to catalyze the reaction of CO2 and alkylene oxide at normal temperature and normal pressure, a yield of the corresponding cyclic carbonate of 35%˜90% can be obtained. The catalyst is easy to recover and the re-use of the catalyst has no influence on the yield; additionally, the yield can reach over 90% by controlling the reaction conditions.

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Patent Owner(s)

Patent OwnerAddress
ZHANGJIAGANG INDUSTRIAL TECHNOLOGY INSTITUTE LTD DALIAN INSTITUTE OF CHEMICAL AND PHYSICS CHINESE ACADEMY OF SCIENCESBUILDING A-2 SHAZHOULAKE HIGH-TECH PARK YANGSHE TOWN ZHANGJIAGANG SUZHOU CITY JIANGSU PROVINCE

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Deng, Weiqiao Dalian, CN 4 50
Liu, Xiaohuan Dalian, CN 6 10
Xie, Yong Dalian, CN 136 763

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