Zeolite porous metal bis(imidazole) coordination polymers and preparation method thereof

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United States of America Patent

PATENT NO 9067956
APP PUB NO 20140088312A1
SERIAL NO

14118158

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The present invention discloses zeolite metal bis(imidazole) coordination polymers and preparation method thereof. The new class of zeolite coordination polymers of the present invention is a chemical compound with the following general chemical formula {[M(BIm)]×xDMF×yC2H6O×zH2O}, in which when M=Zn, x=0.9, y=0, z=0; when M=Cu, x=1.2, y=0, z=0; when M=Mn, x=2.0, y=0, z=0; when M=Ni, x=0.4, y=1.2, z=1.0, BIm is 1,2-bis((5H-imidazol-4-yl)methylene)hydrazine, DMF is N,N-dimethyl formamide, H2O is water. A solvothermal method or slow diffusion is used on the compounds to obtain crystals of high purity. The coordination polymers of the present invention have good thermal stability, and have strong adsorption performance for CO2 under conditions of 0° C. and normal pressure as adsorbent materials.

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Patent Owner(s)

Patent OwnerAddress
SHANTOU UNIVERSITY515063 SHANTOU UNIVERSITY DAXUE ROAD SHANTOU CITY GUANGDONG PROVINCE SHANTOU CITY GUANGDONG PROVINCE 515063

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Li, Dan Shantou, CN 393 4398
Liu, Jie Shantou, CN 812 14130
Zhou, Xiaoping Shantou, CN 78 905

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