Extractive distillation process for benzene recovery

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United States of America Patent

PATENT NO 9005405
APP PUB NO 20130228447A1
SERIAL NO

13410286

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Abstract

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Recovering high purity benzene from hydrocarbon feedstock containing aromatics and non-aromatics is implemented by simple and low-cost modifications to conventional extractive distillation columns (EDCs). Methyl cyclohexane (MCH) that is generated through non-selective hydrogenation of toluene in hydrodesulfurization (HDS) units is a major contaminant in benzene production. To meet MCH specifications, often times the extractive distillation (ED) process for recovering purified benzene is operated with excessive benzene loss to the overhead raffinate stream, producing a lower quality non-aromatic product. Novel techniques (1) remove operational constrictions of the HDS unit on MCH production, thus lengthening the catalyst life and (2) allow the EDC to drive essentially any amount of MCH away from the bottom benzene product without concerns with benzene loss to the overhead raffinate stream and (3) recover benzene from the overhead raffinate stream to upgrade the quality of non-aromatic product and increase the benzene product recovery.

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Patent Owner(s)

Patent OwnerAddress
CPC CORPORATION TAIWANKAOHSIUNG CITY 81126
AMT INTERNATIONAL INC5028 TENNYSON PARKWAY PLANO TX 75024

International Classification(s)

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  • 2012 Application Filing Year
  • C07C Class
  • 3137 Applications Filed
  • 2508 Patents Issued To-Date
  • 79.95 % Issued To-Date

Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Chiu, Tsung-Min Taipei, TW 8 78
Lee, Fu-Ming Katy, US 55 790
Lee, Jeng-Cheng Chia-Yi, TW 8 29
Lin, Tzong-Bin Chia-Yi, TW 31 390
Wu, Kuang-Yeu Plano, US 30 383

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Patent Citation Ranking

  • 1 Citation Count
  • C07C Class
  • 34.61 % this patent is cited more than
  • 10 Age
Citation count rangeNumber of patents cited in rangeNumber of patents cited in various citation count ranges8971459148631652201 - 1011 - 2021 - 3031 - 4041 - 5051 - 6071 - 8001002003004005006007008009001000110012001300140015001600

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