Highly active multidentate catalysts for efficient alkyne metathesis

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United States of America Patent

PATENT NO 8993804
APP PUB NO 20130261295A1
SERIAL NO

13791410

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Abstract

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The invention relates to highly active and selective catalysts for alkyne metathesis. In one aspect, the invention includes a multidentate organic ligand wherein one substrate-binding site of the metal center is blocked. In another aspect, the invention includes N-quaternized or silane-based multidentate organic ligands, capable of binding to metals. In yet another aspect, the invention includes N-quaternized or silane-based multidentate catalysts. The catalysts of the invention show high robustness, strong resistance to small alkyne polymerization and significantly enhanced catalytic activity compared to their corresponding non-quaternized or non-silane-based multidentate catalyst analogs.

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Patent OwnerAddress
THE REGENTS OF THE UNIVERSITY OF COLORADO A BODY CORPORATE1800 GRANT STREET 8TH FLOOR DENVER CO 80203

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Kuthanapillil, Jyothish Boulder, US 3 6
Wang, Qi Qingdao, CN 814 5281
Zhang, Wei Superior, US 2625 19909

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