Process for the preparation of branched polybutadiene with a high content of 1,4-cis units

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United States of America Patent

PATENT NO 8664344
APP PUB NO 20110112261A1
SERIAL NO

12935780

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Abstract

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Process for the preparation of polybutadiene effected by the polymerization of butadiene in an aliphatic and/or cyclo-aliphatic solvent in the presence of a catalytic system prepared in situ which comprises: (i) a carboxylate of neodymium soluble in the process solvent containing a variable quantity of water, the H2O/Nd molar ratio ranging from 0.001/1 to 0.50/1; (ii) an alkyl compound of aluminum; (iii) an alkyl compound of aluminum in which at least one bond of Al consists of an Al—Cl bond; The total Al/Nd molar ratio ranging from 4/1 to 12/1, and the Cl/Nd molar ratio ranging from 2/1 to 6/1.

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Patent Owner(s)

Patent OwnerAddress
POLIMERI EUROPA S P A20097 SAN DONATO MILANESE (MI)

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  • 2009 Application Filing Year
  • C08F Class
  • 1584 Applications Filed
  • 973 Patents Issued To-Date
  • 61.43 % Issued To-Date
Click to zoom InYear of Issuance% of Matters IssuedCumulative IssuancesYearly Issuances20092010201120122013201420152016201720182019202020210255075100

Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Viola, Gian Tommaso Cervia, IT 22 126
Zinna, Marianna Ravenna, IT 4 6

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  • 2 Citation Count
  • C08F Class
  • 15.03 % this patent is cited more than
  • 11 Age
Citation count rangeNumber of patents cited in rangeNumber of patents cited in various citation count ranges246102321869421884331201 - 1011 - 2021 - 3031 - 4041 - 5051 - 6061 - 7071 - 8081 - 9091 - 100100 +050100150200250300350400450500550600650700750800850900950100010501100

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