Method for preparing acrolein from glycerol by catalytic dehydration of glycerol using a heteropolyacid catalyst
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United States of America Patent
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Dec 10, 2013
Grant Date -
Dec 27, 2012
app pub date -
Dec 21, 2010
filing date -
Dec 21, 2009
priority date (Note) -
In Force
status (Latency Note)
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Abstract
The invention relates to a method for preparing acrolein from glycerol or glycerin, according to which dehydration of glycerol or glycerin is carried out in the presence of a catalyst which consists in at least one silica modified with zirconium dioxide, titanium dioxide or tungsten trioxide or any combination of these oxides, and a heteropolyacid. This method may be used for making 3-(methylthio)propionic aldehyde (MMP), 2-hydroxy-4-methylthiobutyronitrile (HMBTN), methionine or its analogs, from acrolein.
First Claim
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Family

- 15 United States
- 10 France
- 8 Japan
- 7 China
- 5 Korea
- 2 Other
Patent Owner(s)
Patent Owner | Address | |
---|---|---|
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE | 3 RUE MICHEL-ANGE PARIS CEDEX 16 F75794 | |
ADISSEO FRANCE S A S | 92160 ANTONY | |
UNIVERSITE LILLE 1-SCIENCES ET TECHNOLOGIES | CITE SCIENTIFIQUE F-59650 VILLENEUVE D'ASCQ |
International Classification(s)

- 2010 Application Filing Year
- C07C Class
- 2897 Applications Filed
- 1740 Patents Issued To-Date
- 60.07 % Issued To-Date
Inventor(s)
Inventor Name | Address | # of filed Patents | Total Citations |
---|---|---|---|
Capron, Mickael | Hasnon, FR | 3 | 8 |
# of filed Patents : 3 Total Citations : 8 | |||
Dumeignil, Franck | Fretin, FR | 16 | 17 |
# of filed Patents : 16 Total Citations : 17 | |||
Katryniok, Benjamin | Loos-en-Gohelle, FR | 7 | 6 |
# of filed Patents : 7 Total Citations : 6 | |||
Paul, Sebastien | Thun Saint-Amand, FR | 5 | 5 |
# of filed Patents : 5 Total Citations : 5 |
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Maintenance Fees
Fee | Large entity fee | small entity fee | micro entity fee | due date |
---|---|---|---|---|
11.5 Year Payment | $7400.00 | $3700.00 | $1850.00 | Jun 10, 2025 |
Fee | Large entity fee | small entity fee | micro entity fee |
---|---|---|---|
Surcharge - 11.5 year - Late payment within 6 months | $160.00 | $80.00 | $40.00 |
Surcharge after expiration - Late payment is unavoidable | $700.00 | $350.00 | $175.00 |
Surcharge after expiration - Late payment is unintentional | $1,640.00 | $820.00 | $410.00 |
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Legal Events
Date | Code | Event | Description |
---|---|---|---|
Mar 07, 2013 | FPAY | FEE PAYMENT | year of fee payment: 12 |
Apr 08, 2009 | FPAY | FEE PAYMENT | year of fee payment: 8 |
Dec 21, 2006 | AS | ASSIGNMENT | free format text: CHANGE OF NAME;ASSIGNOR:COROVIN GMBH;REEL/FRAME:019781/0613 Owner name: FIBERWEB COROVIN GMBH, GERMANY Effective Date: Dec 21, 2006 |
Apr 13, 2005 | FPAY | FEE PAYMENT | year of fee payment: 4 |
Dec 04, 2001 | FEPP | FEE PAYMENT PROCEDURE | free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
Nov 06, 2001 | I | Issuance | |
Oct 18, 2001 | STCF | INFORMATION ON STATUS: PATENT GRANT | free format text: PATENTED CASE |
Mar 30, 1999 | F | Filing | |
Mar 15, 1999 | AS | ASSIGNMENT | free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:NICKEL, AXEL;ETZOLD, STEFAN;REEL/FRAME:010375/0136 Owner name: COROVIN GMBH, GERMANY Effective Date: Mar 15, 1999 |
Aug 01, 1997 | PD | Priority Date |

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