Polymerizable diazonium salts, process for the preparation thereof and uses thereof

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United States of America Patent

PATENT NO 8389696
APP PUB NO 20100184932A1
SERIAL NO

12750424

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Abstract

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Polymerizable diazonium salts having redox properties and absorption in the visible range, a process for preparing them and uses thereof are disclosed. The salts have the general formula:

description='In-line Formulae' end='lead'[XX+LnDdEm(N2+)p][(B)p+x]description='In-line Formulae' end='tail'

in which:

    X is chosen from transition metals, preferably X is chosen from ruthenium (Ru), osmium (Os), iron (Fe), cobalt (Co) and iridium (Ir),x is an integer ranging from 1 to 5 inclusive,L is a ligand chosen from pyridine, bipyridine, terpyridine, phenanthroline and phenylpyridine groups, and mixtures thereof,n is an integer ranging from 1 to 5 inclusive,D is a saturated or unsaturated, C1-C5 alkyl spacer compound,d=0 or 1,E is an aromatic or polyaromatic spacer compound that can contain one or more heteroatoms,m is an integer ranging from 0 to 5 inclusive,p is an integer, andB is a counterion.

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Patent Owner(s)

Patent OwnerAddress
COMMISSARIAT A L'ENERGIE ATOMIQUEPARIS

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Bidan, Gérard Grenoble, FR 3 8
De, Bettignies Rémi St Julien en Genevois, FR 7 4
Jousselme, Bruno Massy, FR 9 23

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