Diadehyde compound, preparation method thereof, and synthetic method of carotenoids using the same
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United States of America Patent
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Apr 17, 2012
Grant Date -
Jul 7, 2011
app pub date -
Mar 14, 2011
filing date -
Jun 5, 2006
priority date (Note) -
Expired
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Abstract
The novel C dialdehyde compound which can be efficiently utilized in the synthesis of carotenoid compounds based on the sulfone chemistry, the preparation method of the same, and the expeditious and practical synthetic processes for lycopene and β-carotene by the use of the above novel compound are disclosed. The syntheses of lycopene and β-carotene are characterized by the processes of the coupling reaction between two equivalents of geranyl sulfone or cyclic geranyl sulfone and the above C dialdehyde, the functional group transformation reactions of the diol in the resulting C 40 coupling products to X's (either halogens or ethers), and the double elimination reactions of the functional groups of the benzenesulfonyl and X to produce the fully conjugated polyene chain of the carotenoids.
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