Hydrogen storage alloys having improved cycle life and low temperature operating characteristics

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United States of America Patent

PATENT NO 7393500
APP PUB NO 20040219053A1
SERIAL NO

10817267

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Abstract

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Electrochemical and gas phase hydrogen storage alloy compositions that provide superior performance, especially at low temperature, and excellent cycle life characteristics. The alloys of this invention are AB.sub.5 type alloys that include a cycle life enhancement element and a low Co concentration. The preferred cycle life enhancement elements include Zr and Si. The cycle life enhancement elements increase the cycle life of the instant alloys by reducing the pulverization of alloy particles upon repeated cycles of charging-discharging or hydriding-dehydriding. The alloys are characterized by low hysteresis on cycling, where hysteresis is measured in terms of mass concentration difference, a parameter related to the activation energy associated with the incorporation of hydrogen into the alloy. The instant alloys are designed to have a low activation energy for hydrogen incorporation and as a result, provide low hysteresis and a more uniform concentration of absorbed hydrogen within the material. As a result, differential lattice expansion effects associated with the absorption of hydrogen are minimized and the tendency for particle pulverization on cycling is minimized. Alloys having a low Co concentration and long cycle life are thus provided for.

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Patent Owner(s)

Patent OwnerAddress
CHEVRONTEXACO TECHNOLOGY VENTURES LLC3901 BRIARPARK HOUSTON TX 77042-5301

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Fetcenko, Michael A Rochester, MI 90 1133
Ouchi, Taihei Rochester, MI 19 52
Ovshinsky, Stanford R Bloomfield Hills, MI 371 21172
Young, Kwo Troy, MI 80 470

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