Process for the dissolution of actinic oxides

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United States of America Patent

PATENT NO 7238270
APP PUB NO 20060110303A1
SERIAL NO

10528905

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ATTORNEY / AGENT: (SPONSORED)

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Abstract

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The invention provides a process for dissolving actinic oxides, the process comprising performing the steps of (a) introducing the actinic oxides into a solution of nitric acid; (b) treating the acidic solution in order to substantially remove palladium; and (c) treating with divalent silver. Preferably, the actinic oxides are comprised in spent nuclear fuel. Optionally, the process comprises a second treatment of the acidic solution in order to substantially remove palladium and a second treatment with divalent silver. The steps may be performed on a batchwise or continuous basis. The treatment to remove palladium is preferably carried out by solvent extraction or ion exchange, and provides greatly improved rates of dissolution of oxides of plutonium. The treatment with divalent silver preferably involves the addition of a source of monovalent silver, followed by an electrolysis treatment to generate divalent silver.

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Patent Owner(s)

Patent OwnerAddress
BRITISH NUCLEAR FUELS PLCRISLEY WARRINGTON CHESHIRE WA3 6AS

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Bernard, Robert John Cockermouth, GB 1 0
Rance, Peter Jonathan Watson St. Bees, GB 4 6

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