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Abstract

A laser-engravable flexographic printing element comprising an elastomeric, relief-forming, laser-engravable, thermally and/or photochemically crosslinkable layer comprising, as binder, at least 5% by weight of syndiotactic 1,2-polybutadiene having a content of 1,2-linked butadiene units of from 80 to 100%, a degree of crystallinity of from 5 to 30% and a mean molecular weight of from 20,000 to 300,000 g/mol on a flexible, dimensionally stable support.The elastomeric, relief-forming, laser-engravable layer preferably comprises: (a) from 50 to 99.9% by weight of one or more binders as component A consisting of (a1) from 5 to 100% by weight of syndiotactic 1,2-polybutadiene having a content of 1,2-linked butadiene units of from 80 to 100%, a degree of crystallinity of from 5 to 30% and a mean molecular weight of from 20,000 to 300,000 g/mol as component A1, and (a2) from 0 to 95% by weight of further binders as component A2, (b) from 0.1 to 30% by weight of crosslinking, oligomeric plasticizers which contain reactive groups in the main chain and/or reactive pendant and/or terminal groups as component B, (c) from 0 to 25% by weight of ethylenically unsaturated monomers as component C, (d) from 0 to 10% by weight of photoinitiators and/or thermally decomposable initiators as component D, (e) from 0 to 20% by weight of absorbers for laser radiation as component E, and (f) from 0 to 30% by weight of further conventional additives as component F.

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