O-acyloxime photoinitiators

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United States of America Patent

PATENT NO 6596445
SERIAL NO

09338152

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Abstract

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Oximeester compounds of the formulae I, II, III and IV ##STR1## wherein R.sub.1 is phenyl, C.sub.1 -C.sub.20 alkyl or C.sub.2 -C.sub.20 alkyl optionally interrupted by --O--, C.sub.2 -C.sub.20 alkanoyl or benzoyl, or R.sub.1 is C.sub.2 -C.sub.12 alkoxycarbonyl or phenoxycarbonyl; R.sub.1 ' is C.sub.2 -C.sub.12 alkoxycarbonyl, or R.sub.1 ' is phenoxycarbonyl, or R.sub.1 ' is --CONR.sub.10 R.sub.11 or CN; R.sub.2 is C.sub.2 -C.sub.12 alkanoyl, C.sub.4 -C.sub.6 alkenoyl, benzoyl, C.sub.2 -C.sub.6 alkoxycarbonyl or phenoxycarbonyl; R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are hydrogen, halogen, C.sub.1 -C.sub.12 alkyl, cyclopentyl, cyclohexyl, phenyl, benzyl, benzoyl, C.sub.2 -C.sub.12 alkanoyl, C.sub.2 -C.sub.12 alkoxycarbonyl, phenoxycarbonyl or a group OR.sub.8, SR.sub.9, SOR.sub.9, SO.sub.2 R.sub.9 or NR.sub.10 R.sub.11 ; R.sub.4 ', R.sub.5 ' and R.sub.6 ' are hydrogen, halogen, C.sub.1 -C.sub.12 alkyl, cyclopentyl, cyclohexyl, phenyl, benzyl, benzoyl, C.sub.2 -C.sub.12 -alkanoyl, C.sub.2 -C.sub.12 alkoxycarbonyl, phenoxycarbonyl, or are a group OR.sub.8, SR.sub.9, SOR.sub.9, SO.sub.2 R.sub.9, NR.sub.10 R.sub.11 ; provided that at least one of R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R'.sub.4, R'.sub.5 and R'.sub.6 is OR.sub.8, SR.sub.9 or NR.sub.10 R.sub.11 ; R.sub.8, R.sub.9, R.sub.10 and R.sub.11 are for example hydrogen, C.sub.1 -C.sub.12 alkyl, phenyl; are suitable as initiators for the photopolymerization of radically polymerizable compounds.

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Patent Owner(s)

Patent OwnerAddress
BASF SELUDWIGSHAFEN GERMANY LUDWIGSHAFEN RHINELAND-PALATINATE

International Classification(s)

Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Birbaum, Jean-Luc Binningen, CH 46 986
Dietliker, Kurt Allschwil, CH 47 1067
Kura, Hisatoshi Hyogo, JP 51 1429
Matsumoto, Akira Kyoto, JP 285 2336
Ohwa, Masaki Kobe, JP 34 1452
Oka, Hidetaka Hyogo, JP 20 976

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