Multi-stage process for the polymerization of olefins

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United States of America Patent

PATENT NO 6479609
SERIAL NO

09883514

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Abstract

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A multi-stage process for preparing ethylene (co)polymers having broad molecular weight distributions is disclosed, said process comprising: (A) a first polymerization stage in which, in the presence of a Ti or V catalyst, a first ethylene polymer is prepared; (B) a treatment stage in which the catalyst used in the first stage is deactivated and in which a bridged bis-2-indenyl zirconocene is supported on the ethylene polymer produced in stage (A), optionally in the presence of a suitable cocatalyst; and (C) a second polymerization stage in which ethylene is polymerized in the presence of the product obtained from stage (B). Furthermore, polyethylene obtainable by the above process is disclosed, having intrinsic viscosity ranging from 0.5 to 6 dl/g, Mw/Mn>8 and cold xylene solubility<1.2 % wt.

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Patent Owner(s)

Patent OwnerAddress
BASELL TECHNOLOGY COMPANY BVHOEKSTEEN 66 HOOFDDORP

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Baruzzi, Giovanni Ferrara, IT 18 347
Dall'Occo, Tiziano Ferrara, IT 57 434
Schaverien, Colin J Amsterdam, NL 6 108

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