Process for the catalytic preparation of aldehydes from olefins using ligand mixtures

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United States of America Patent

PATENT NO 6403837
SERIAL NO

09708624

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Abstract

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A process for preparing aldehydes having from 4 to 25 carbon atoms by catalytic hydroformylation of the corresponding olefins, wherein the catalyst used comprises a metal of transition group 8 of the Periodic Table in the presence of a ligand A of the formula I ##STR1## where X=As, Sb or P and R.sup.1,R.sup.2,R.sup.3 : are each a substituted or unsubstituted aliphatic, cycloaliphatic or aromatic hydrocarbon radical having from 1 to 50 carbon atoms, where two of the radicals R.sup.1, R.sup.2, R.sup.3 can be covalently linked with the proviso that at least one of the hydrocarbon radicals R.sup.1, R.sup.2, R.sup.3 contains a heteroatom selected from the group consisting of O, S, N, F, Cl, Be, I, Se and Te, and a ligand B of the formula II ##STR2## where R.sup.4, R.sup.5, R.sup.6 : are each a substituted or unsubstituted aliphatic, cycloaliphatic or aromatic hydrocarbon having from 1 to 50 carbon atoms, where two of the radicals R4, R5 and R6 can be covalently linked.

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Patent Owner(s)

Patent OwnerAddress
OXENO OLEFINCHEMIE GMBH45772 MARL

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Boerner, Armin Rostock, DE 29 210
Hess, Dieter Marl, DE 82 699
Roettger, Dirk Recklinghausen, DE 35 400
Selent, Detlef Berlin, DE 44 239

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