Process for preparing higher oxo alcohols from olefin mixtures by two-stage hydroformylation

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United States of America Patent

PATENT NO 6331657
SERIAL NO

09396371

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Abstract

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A process for preparing higher oxo alcohols from mixtures of isomeric olefins having from 5 to 24 carbon atoms by two-stage hydroformylation in the presence of a cobalt catalyst or rhodium catalyst at elevated temperature and at elevated pressure, which comprises selectively hydrogenating the first hydroformylation stage reaction mixture, separating the hydrogenation mixture in a distillation into crude alcohol and low-boilers predominantly consisting of olefins, passing these low-boilers to the second hydroformylation stage, again selectively hydrogenating the second hydroformylation stage reaction mixture, separating the hydrogenation mixture in one distillation into crude alcohol and low-boilers, working up the crude alcohol by distillation to pure alcohol and taking off at least some of the low-boilers to discharge saturated hydrocarbons.

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Patent Owner(s)

Patent OwnerAddress
OXENO OLEFINCHEMIE GMBH45764 MARL

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Bueschken, Wilfried Haltern, DE 55 708
Kaizik, Alfred Marl, DE 49 893
Nierlich, Franz Marl, DE 46 612
Scholz, Bernhard Marl, DE 47 1130
Toetsch, Walter Marl, DE 11 214

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