Process for preparing polyethylene naphthalate based polymers by using NDCA or its derivates

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United States of America Patent

PATENT NO 6323305
SERIAL NO

09589267

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Abstract

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The present invention provides a process for preparing polyethylene naphthalate polymers comprising: esterifying a slurry comprising NDCA or a dicarboxylic acid containing NDCA or derivatives thereof, and ethylene glycol or a glycol containing ethylene glycol or derivatives thereof to produce esterification compounds comprising bis (beta-hydroxyethyl) naphthalate or low molecular weight polymers thereof, wherein one or more primary alcohol is added to the slurry; and polycondensing the above resultant esterification compounds to produce polyethylene naphthalate polymers. The process of the present invention allows for the preparation of a slurry more easily and to maximize the manufacturing efficiency. Ultimately, it is possible to increase the productivity of the PEN polymers and to obtain high quality PEN since the method of the present invention has an effect of minimizing side products of the polymerization by reducing the amount of ethylene glycol considerably and of shortening the reaction time of the esterification reaction.

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Patent Owner(s)

Patent OwnerAddress
KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYSEOUL SOUTH KEREAN
S-OIL CORPORATIONSEOUL

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Cho, Hyun Nam Seoul, KR 38 570
Choi, Il Seok Kyungki-do, KR 6 7
Hong, Jae Min Seoul, KR 14 71
Ko, Young Chan Seoul, KR 17 67
Lee, Hyoung-Wook Kyungki-Do, KR 17 188

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