Process for producing polytetramethylene ether glycol diester on aluminium magnesium silicate catalysis

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United States of America Patent

PATENT NO 6271413
SERIAL NO

08913553

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Abstract

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An improved process for the preparation of polytetramethylene ether glycol diesters of the formula R--CO--O(--CH.sub.2 -CH.sub.2 -CH.sub.2 -CH.sub.2 -O).sub.n -COR.sub.1 in which R and R.sub.1 are identical or different and are an alkyl radical or a derivative thereof, by polymerization of tetrahydrofuran in the presence of a fixed-bed polymerization catalyst and a carboxylic acid anhydride. Through use of neutral or weakly basic magnesium-aluminium hydrosilicates instead of the known acidic montmorillonite, zeolite or kaolin catalysts, polymers with more uniform properties and a narrower molecular weight distribution are obtained at a higher rate of polymerization, even when technical-grade tetrahydrofuran is used.

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Patent Owner(s)

Patent OwnerAddress
KOREA PTG CO LTDULSAN 680-150

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Muller, Herbert Frankenthal, DE 32 170

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