Process for the gas-phase polymerization of olefins
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United States of America Patent
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May 8, 2001
Grant Date -
N/A
app pub date -
Jun 7, 1995
filing date -
Jun 3, 1991
priority date (Note) -
Expired
status (Latency Note)
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Abstract
Process for the gas-phase polymerization of olefins of the formula CH.sub.2.dbd.CHR where R is hydrogen or an alkyl or aryl radical with 1 to 8 carbon atoms carried out in one or more reactors having a fluidized or mechanically agitated bed, using a catalyst obtained by reaction of a titanium halide or haloalcoholate and optionally an electron-donor compound supported on an active Mg-dihalide with an Al-trialkyl compound and optionally an electron-donor compound, comprising the steps of: a) contacting the catalyst components in the absence of polymerizable olefin or optionally in the presence of said olefin in an amount to from up to 3 g per g of solid catalyst component; b) prepolymerizing propylene or mixtures of propylene with ethylene or an alpha-olefin to form a propylene polymer having an insolubility in xylene of at least 60% by weight, in an amount of from 5 g of polymer per g of solid catalyst component to 10% by weight of the final catalyst yield; and c) polymerizing one or more CH.sub.2.dbd.CHR olefins in the gas phase in the presence of the prepolymer-catalyst system obtained in b), while maintaining in the gas phase an alkane in a molar concentration with respect to the total gases of from 20 to 90%.

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Patent Owner(s)
Patent Owner | Address | |
---|---|---|
MONTELL TECHNOLOGY COMPANY BV | HOEKSTEEN 66 HOOFDDORP |
International Classification(s)
Inventor(s)
Inventor Name | Address | # of filed Patents | Total Citations |
---|---|---|---|
Covezzi, Massimo | Ferrara, IT | 37 | 496 |
Galli, Paolo | Ferrara, IT | 14 | 516 |
Govoni, Gabriele | Ferrara, IT | 36 | 924 |
Rinaldi, Roberto | Mantova, IT | 24 | 343 |
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Fee | Large entity fee | small entity fee | micro entity fee |
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Surcharge after expiration - Late payment is unavoidable | $700.00 | $350.00 | $175.00 |
Surcharge after expiration - Late payment is unintentional | $1,640.00 | $820.00 | $410.00 |
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