Process for the gas-phase polymerization of olefins

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United States of America Patent

PATENT NO 6228956
SERIAL NO

08476063

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Abstract

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Process for the gas-phase polymerization of olefins of the formula CH.sub.2.dbd.CHR where R is hydrogen or an alkyl or aryl radical with 1 to 8 carbon atoms carried out in one or more reactors having a fluidized or mechanically agitated bed, using a catalyst obtained by reaction of a titanium halide or haloalcoholate and optionally an electron-donor compound supported on an active Mg-dihalide with an Al-trialkyl compound and optionally an electron-donor compound, comprising the steps of: a) contacting the catalyst components in the absence of polymerizable olefin or optionally in the presence of said olefin in an amount to from up to 3 g per g of solid catalyst component; b) prepolymerizing propylene or mixtures of propylene with ethylene or an alpha-olefin to form a propylene polymer having an insolubility in xylene of at least 60% by weight, in an amount of from 5 g of polymer per g of solid catalyst component to 10% by weight of the final catalyst yield; and c) polymerizing one or more CH.sub.2.dbd.CHR olefins in the gas phase in the presence of the prepolymer-catalyst system obtained in b), while maintaining in the gas phase an alkane in a molar concentration with respect to the total gases of from 20 to 90%.

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Patent Owner(s)

Patent OwnerAddress
MONTELL TECHNOLOGY COMPANY BVHOEKSTEEN 66 HOOFDDORP

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Covezzi, Massimo Ferrara, IT 37 496
Galli, Paolo Ferrara, IT 14 516
Govoni, Gabriele Ferrara, IT 36 924
Rinaldi, Roberto Mantova, IT 24 343

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