Ruthenium-containing catalyst system for olefin metathesis

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United States of America Patent

PATENT NO 6159890
SERIAL NO

09181352

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Abstract

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A ruthenium-containing metathesis catalyst system which contains a ruthenium compound (A), a phosphorus, arsenic, or antimony compound (B), and a compound (C) containing at least one carbon-to-carbon triple bond. The mole ratio of compounds A:B:C is typically in the range of about 1.0:0.01-100:0.01-500. The ruthenium compound (A) is a Ru(II), Ru(III), or Ru(IV) compound containing an anionic ligand (X) and optionally an arene ligand and optionally a phosphorus, arsenic, or antimony compound ligand. The compound (B) is optional if the ruthenium compound (A) contains a phosphorus-, arsenic-, or antimony-containing ligand. Hydrogen gas is used as an activator. A process for metathesis of olefins involves reacting at least one olefin with the catalyst system described herein.

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Patent Owner(s)

Patent OwnerAddress
BP AMOCO CORPORATIONLAW DEPT MAIL CODE 1907A 200 EAST RANDOLPH DR CHICAGO IL 60601

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Choi, David S Naperville, IL 12 133
Hunt, Craig Lane Naperville, IL 2 22
Marks, Tobin J Evanston, IL 194 3112
Nubel, Philip O Naperville, IL 24 412

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