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Abstract

Electrolyte systems for lithium batteries of increased safety comprise at least one lithium-containing conducting salt and at least one electrolyte fluid and, according to the invention, are defined by at least one partially fluorinated carbamate of general formula (I) ##STR1## where R.sup.1 and R.sup.2 independently of one another or identical or different, linear C.sub.1 -C.sub.6 -alkyl, branched C.sub.3 -C.sub.6 -alkyl, C.sub.3 -C.sub.7 -cycloalkyl or R.sup.1 and R.sup.2 directly or via one or more additional nitrogen and/or oxygen atoms are linked to form a ring having from 3 to 7 ring members, and the additional nitrogen atoms present in the ring being substituted with C.sub.1 -C.sub.3 -alkyl and the ring carbon atoms optionally carrying C.sub.1 -C.sub.3 -alkyl, with the option of one or more hydrogen atoms in the radicals R.sup.1 and R.sup.2 being replaced by fluorine atoms, R.sup.3 is a partially fluorinated or perfluorinated straight-chain alkyl group having from 1 to 6 carbon atoms, is a partially fluorinated or perfluorinated branched alkyl group having from 3 to 6 carbon atoms or a partially fluorinated cycloalkyl group having from 3 to 7 carbon atoms, which optionally be monosubstituted or polysubstituted with C.sub.1 -C.sub.6 -alkyl.

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First Claim