Process for the production of olefinic polymers

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United States of America Patent

PATENT NO 6111040
SERIAL NO

09017780

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ATTORNEY / AGENT: (SPONSORED)

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Abstract

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A catalyst comprises a composition resulting from mutual contact of the following Components. (A), (B), (C) and (D): said Component (A) being a reaction product resulting from mutual contact of components (a), (b) and (c); said component (a) being represented by the formula Me.sup.1 R.sup.1.sub.p (OR.sup.2).sub.q X.sup.1.sub.4-p-q I wherein R.sup.1 and R.sup.2 each are a C.sub.1 -C.sub.24 hydrocarbon moieties, X.sup.1 is a hydrogen atom or a halogen atom, Me.sup.1 is titanium, zirconium or hafnium, p and q are 0.ltoreq.p.ltoreq.4, 0.ltoreq.q.ltoreq.4 and 0.ltoreq.p+q.ltoreq.4, said component (b) being represented by the formula Me.sup.2 R.sup.3.sub.m (OR.sup.4).sub.n X.sup.2.sub.z-m-n II wherein R.sup.3 and R.sup.4 each are a C.sub.1 -C.sub.2 4 hydrocarbon moieties, X.sup.2 is a hydrogen atom or a halogen atom, Me.sup.2 is an element of Groups I to III in the Periodic Table, z is a valence of Me.sup.2, and m and n are 0.ltoreq.m.ltoreq.z, 0.ltoreq.n.ltoreq.z and 0.ltoreq.m+n.ltoreq.z, and said component (c) being an organocyclic compound having two or more conjugated double bonds; said Component (B) being a modified organoaluminum compound having Al-O-Al bonds; said Component (C) being an organocyclic compound having two or more conjugated double bonds which is different from component (c); and said Component (D) being an inorganic carrier or particulate polymer carrier. The disclosed catalyst find extensive use in the manufacture of olefinic polymers having a relatively high molecular weight and a relatively wide molecular weight distribution as well as olefinic copolymers having a relatively narrow composition distribution.

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Patent Owner(s)

Patent OwnerAddress
JAPAN POLYOLEFINS CO LTD26-5 TORANOMON 1-CHOME MINATO-KU TOKYO

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Matsuura, Kazuo Kawasaki, JP 160 1952
Sano, Akira Kawasaki, JP 120 683
Shimizu, Hiroyuki Kawasaki, JP 162 1480

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