Process for preparing tertiary alkyl ethers

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United States of America Patent

PATENT NO 5998675
SERIAL NO

09091651

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ATTORNEY / AGENT: (SPONSORED)

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Abstract

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A process for preparing tertiary alkyl ethers comprises the steps of reacting C.sub.4-7 isoolefins of an olefinic hydrocarbon feedstock with an alkanol in the presence of a first catalyst in a reaction zone to form a reaction mixture containing a tertiary alkyl ether or a mixture of tertiary alkyl ethers, feeding the reaction mixture to a distillation column, distilling the reaction mixture and recovering the alkyl ether(s) with the bottoms product of the distillation. An azeotrope formed by unreacted C.sub.4 hydrocarbons and the alkanol is withdrawn as an overhead product of the distillation. According to the invention, a part of the liquid flow of the column is withdrawn to form a side drawoff, and the side drawoff is recirculated to the reaction zone. As a result, the conversion of the reactive C.sub.6 hydrocarbons is increased and the operating cost of the ethers process is reduced.

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Patent Owner(s)

Patent OwnerAddress
NESTE OYKEILANIEMI 02150 ESPOO

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Lindqvist, Petri Porvoo, FI 31 101

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