Secondary and tertiary phosphines and processes for their preparation

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United States of America Patent

PATENT NO 5925785
SERIAL NO

08821715

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ATTORNEY / AGENT: (SPONSORED)

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Abstract

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The invention relates to secondary and tertiary phosphines of the formula ##STR1## in which R is hydrogen, an aryl or benzyl group or a straight-chain or branched alkyl group, n is 1 or 2 and M is potassium or sodium. These phosphines are prepared by reacting either alkali metal salts of fluorobenzene-2,4-disulfonic acid with phosphine or with primary or secondary phosphines, or secondary phosphines of the type HP?C.sub.6 H.sub.3 -2,4-(SO.sub.3 M).sub.2 !.sub.2 with a compound RX in which R is an alkyl, aryl or benzyl group and X is a halogen, in an aprotic solvent in the presence of at least stoichiometric quantities of a solid, powdered alkali metal hydroxide at temperatures of from 0 to 100.degree. C.

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Patent Owner(s)

Patent OwnerAddress
CELANESE GMBH60439 FRANKFURT

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Herd, Oliver Wuppertal, DE 3 13
Stelzer, Othmar Wuppertal, DE 6 23
Weferling, Norbert Hurth, DE 38 468

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