Electrochemical synthesis of transition metal/phosphine catalysts

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United States of America Patent

PATENT NO 5876587
SERIAL NO

08777392

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Abstract

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Catalyst compounds comprising at least one transition metal in an oxidation state of 0 to 1, and at least one monodentate or bidentate water-soluble phosphine, well suited for the hydrocyanation of ethylenically unsaturated compounds, are electrochemically synthesized, by electrolyzing an aqueous solution catholyte (contained in the cathode compartment of any suitable electrolytic cell) comprising at least one transition metal compound and at least one monodentate or bidentate water-soluble phosphine, advantageously at least one phosphine having the following formulae (I) and/or (II): P(Ar1).sub.a (Ar2).sub.b (Ar3).sub.c (D1).sub.d (D2).sub.e (D3).sub.f(I) (Ar1).sub.a (Ar2).sub.b (D1).sub.d (D2).sub.e P-L-P(Ar1).sub.g (Ar2).sub.h (D1).sub.i (D2).sub.j (II).

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Patent Owner(s)

Patent OwnerAddress
R P FIBER & RESIN INTERMEDIATES25 QUAI PAUL DOUMER 92408 COURBEVOIE CEDEX

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Horbez, Dominique Franconville, FR 14 54
Huser, Marc Villeurbanne, FR 14 90
Perron, Robert Charly, FR 48 234

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