Recovery of anhydrous acids

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United States of America Patent

PATENT NO 5873981
SERIAL NO

08773116

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Abstract

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A is a process for removing water from an alkanesulfonic acid such as methanesulfonic acid or ethanesulfonic acid by mixing an azeotropic excess of a phenolic compound with water and the alkanesulfonic acid, then boiling off substantially all of the water, and leaving as a remnant substantially all the alkanesulfonic acid and some of the phenol. This process is particularly useful for recycling an alkanesulfonic acid for a reaction which requires the phenolic compound as one of the reagents. One such reaction is the alkanesulfonic acid catalyzed condensation reaction of a phenolic compound with an .alpha.haloketone to form a chlorinated intermediate of a dihydroxy-.alpha.-alkylstilbene such as 4,4'-dihydroxy-.alpha.-alkylstilbene (DHAMS).

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Patent Owner(s)

Patent OwnerAddress
MICHIGAN MOLECULAR INSTITUTE1910 WEST SAINT ANDREWS ROAD MIDLAND MI 48640

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Clement, Katherine S Lake Jackson, TX 30 967
Nguyen, Son T Lake Jackson, TX 57 5303
Walker, Louis L Clute, TX 35 413

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