Propylene polymers

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United States of America Patent

PATENT NO 5773516
SERIAL NO

08761341

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Abstract

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Propylene polymers which comprise from 25 to 97% by weight of a propylene polymer (I) containing from 0 to 15% by weight of copolymerized C.sub.2 -C.sub.10 -alk-1-enes and also comprise from 3 to 75% by weight of a further propylene polymer (II) containing from 15 to 80% by weight of copolymerized C.sub.2 -C.sub.10 -alk-1-enes, are obtainable by two-stage polymerization of propylene and C.sub.2 -C.sub.10 -alk-1-enes in the presence of a Ziegler-Natta catalyst system which comprises a titanium-containing solid component a) comprising a compound of magnesium, a halogen, silica gel as support and a carboxylic ester as electron donor compound, and also as cocatalysts an aluminum compound b) and a further electron donor compound c), where, in a first polymerization stage, propylene is polymerized in the presence or absence of further C.sub.2 -C.sub.10 -alk-1-enes at from 50.degree. to 100.degree. C., pressures in the range from 15 to 40 bar and a mean residence time of from 0.5 to 5 hours and subsequently, in a second polymerization stage, a mixture of propylene and further C.sub.2 -C.sub.10 -alk-1-enes is polymerized at from 30.degree. to 100.degree. C., pressures in the range from 15 to 40 bar and mean residence times of from 0.5 to 5 hours onto the propylene polymer obtained from the first polymerization stage, and the silica gel used as support for the titanium-containing solid component has a mean particle diameter of from 5 to 200 .mu.m, a mean particle diameter of the primary particles of from 1 to 10 .mu.m and voids or channels having a mean diameter of from 1 to 10 .mu.m, which voids or channels have a macroscopic volume as a proportion of the total particle in the range from 5 to 20%.

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Patent Owner(s)

Patent OwnerAddress
NOVOLEN TECHNOLOGY HOLDINGS C VOOSTDUINLAAN 75 2596 JJ THE HAGUE

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Huffer, Stephan Ludwigshafen, DE 55 345
Kersting, Meinolf Neustadt, DE 23 214
Kerth, Jurgen Carlsberg, DE 15 147
Langhauser, Franz Bad Durkheim, DE 53 719
Muller, Patrik Kaiserslautern, DE 21 184
Seelert, Stefan Frankenthal, DE 10 120
Werner, Rainer Alexander Bad Durkheim, DE 5 46

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