Preparation of pentenoic acids via hydroxycarbonylation of butadiene

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United States of America Patent

PATENT NO 5763655
SERIAL NO

08635493

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Abstract

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Pentenoic acids are selectively prepared via hydroxycarbonylation of butadiene with carbon monoxide and water, at a temperature above 30.degree. C., under a partial pressure of carbon monoxide, measured at 25.degree. C., equal to or greater than 0.5 bar, in the presence of a catalytically effective amount of an iridium-based catalyst and an iodine-containing or bromine-containing promoter therefor, in a solvent medium, wherein the iodine or bromine/iridium molar ratio is less than or equal to 20/1 and the concentration by weight of water in the reaction mixture is less than or equal to 8%.

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Patent Owner(s)

Patent OwnerAddress
R P FIBER & RESIN INTERMEDIATES25 QUAI PAUL DOUMER 92408 COURBEVOIE CEDEX

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Patois, Carl Lyons, FR 13 22
Perron, Robert Charly, FR 48 234

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