Recovery of valuable substances

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United States of America Patent

PATENT NO 5665324
SERIAL NO

08502671

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Abstract

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Valuable substances are recovered from a spent electroless nickel plating solution containing a water-soluble nickel salt, organic complexing agent, hypophosphite, phosphite, and alkali metal ion by adding oxalic acid to the plating solution for causing a nickel ion to precipitate as nickel oxalate for removal and recovery; optionally adding a sulfide to the plating solution for causing a heavy metal ion to precipitate as a heavy metal sulfide for removal; adding a mineral acid and calcium oxide, calcium hydroxide, calcium carbonate, calcium sulfate, calcium chloride or a calcium salt of organic acid to the plating solution from which the nickel ion has been removed; firing solids of the solution in air for converting the alkali metal ion into an alkali metal salt of mineral acid, converting phosphorus into hydroxyapatite, and pyrolyzing off the organic material; and pouring a solid mixture of the alkali metal salt of mineral acid and hydroxyapatite into water for dissolving the alkali metal salt of mineral acid in water for separate recovery of hydroxyapatite and the alkali metal salt of mineral acid.

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Patent Owner(s)

Patent OwnerAddress
C UYEMURA & CO LTDOSAKA JAPAN
TAINEI CHEMICAL INDUSTRIAL CO LTDOSAKA-SHI 1-16 HIGASHI KORAIBASHI CHUO-KU OSAKA

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Araki, Ken Hirakata, JP 10 98
Furui, Takashi Hirakata, JP 27 273
Izawa, Teruyoshi Kasugai, JP 1 10
Kani, Yoshihiro Tajimi, JP 1 10
Kato, Tamotsu Hirakata, JP 3 18
Kudo, Kazunori Mizunami, JP 33 885

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