Continuous process for the aminolysis of ethylene copolymers
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United States of America Patent
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Mar 12, 1996
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N/A
app pub date -
Jan 14, 1994
filing date -
Jan 14, 1994
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Abstract
A continuous process for the aminolysis of polymers produced from ethylenically unsaturated structural units comprising contacting, in a reaction vessel, (a) a molten polymer containing structural units produced from alpha-olefins having from 2 to 8 carbons atoms, and esters of of .alpha.,.beta.-ethylenically-unsaturated carboxylic acids in a reaction vessel; and (b) a liquid phase comprising an amine-containing compound, e.g., an alkylamine having an alkyl group containing 1-30 carbon atoms, ammonia, or derivatives thereof, in the presence of (c) a catalytically effective amount of a catalyst, which is preferably a metal-containing solution, for a period of time effective to produce a polymer containing acrylamide structural units, wherein the period of time is less than about 1 hour. This process is performed continuously in a reaction vessel, preferably in at least one reactive extruder, under conditions effective to provide an ethylene co-polymer containing acrylamide structural units.
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