Temporary inactivation of serine hydrolases using nitrophenyl phenacyl phosphonates
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United States of America Patent
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Jan 25, 1994
Grant Date -
N/A
app pub date -
Mar 4, 1992
filing date -
Mar 4, 1992
priority date (Note) -
Expired
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Abstract
Phenacyl phosphonate adducts of serine hydrolases temporarily inactivate the hydrolases. The hydrolases are reactivated by intramolecularly catalyzed dephosphonylation of the adduct over a period of time. Half-lives for dephosphonylation in the range of about 30 to 500 minutes have been observed at physiological pH's.
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