Optical element having non-linear optical properties

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United States of America Patent

PATENT NO 4981612
SERIAL NO

07190433

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ATTORNEY / AGENT: (SPONSORED)

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Abstract

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An optical element, such as a wave guide, having non-linear optical properties, suitable for use in optical devices in which it is desirable to alter the characteristics of the light, comprising a transparent or reflecting substrate having at least a partial superficial coating comprising alternating monolayers of a first non-linear optical (NLO) compound of the formula: ##STR1## wherein R is an non-hydrophilic aliphatic or cycloaliphatic group containing from 8 to 40 carbon atoms; m is 1 or 2; R.sup.1 is NO.sub.2, CN or COOR.sup.2 ; R.sup.2 is H or C.sub.1-4 -alkyl; n is from 1 to 4; and R.sup.3 is H, a metal or a group containing a tetravalent N atom and a second NLO compound of the formula: ##STR2## wherein T is H, a metal or a group containing a tetravalent N atom; X is S, O, ##STR3## T.sup.1 is NO.sub.2, CN or COOY; Y is selected from H, C.sub.1-4 -alkyl, a metal or a group containing a tetravalent N atom; T.sup.2 and T.sup.3 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms; T.sup.4 and T.sup.5 are each independently H or a non-hydrophilic aliphatic or cycloaliphatic group containing up to 30 carbon atoms; and T.sup.6 and T.sup.7 are each independently H or a non-hydrophilic group containing up to 4 carbon atoms; or T.sup.4 and T.sup.6 together comprise ring fused to Ring A and T.sup.5 and T.sup.7 are as hereinbefore defined; or T.sup.5 and T.sup.7 together comprise ring fused to Ring A and T.sup.4 and T.sup.6 are as hereinbefore defined; or T.sup.2 and T.sup.4 together with the N atom to which T.sup.2 is attached form a ring fused to Ring A and T.sup.3 and T.sup.5 are as hereinbefore defined; or T.sup.3 and T.sup.5 together with the N atom to which T.sup.3 is attached form a ring fused to Ring A and T.sup.2 and T.sup.4 are as hereinbefore defined; provided there are, in total, from 8 to 40 carbon atoms in one or two of the groups independently represented by T.sup.2, T.sup.3, T.sup.4 and T.sup.5.

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Patent Owner(s)

Patent OwnerAddress
IMPERIAL CHEMICAL INDUSTRIES PLCIMPERIAL CHEMICAL HOUSE A CORP OF GREAT BRITAIN MILLBANK LONDON SW1P 3JF
CENTRE NATIONAL D'ETUDES DES TELECOMMUNICATIONSF-92131 ISSY LES MOULINEAUX

International Classification(s)

Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Allen, Simon Cheadle Hulme, GB2 16 41
Gordon, Paul F Rochdale, GB2 12 102
Zyss, Joseph Bagneux, FR 16 83

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