Recovery of acrylic acid and/or ethyl acrylate from black acid

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United States of America Patent

PATENT NO 4968834
SERIAL NO

07521294

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Abstract

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Black acid or the sulfuric acid residue obtained in the manufacture of ethyl acrylate by reaction of ethylene and acrylic acid in the presence of sulfuric acid is heated and distilled in a distillation zone in the presence of a solvent to form an overhead mixture comprising an organic phase containing ethyl acrylate and solvent, and an aqueous phase containing water, solvent and acrylic acid. The aqueous phase is recycled to the distillation zone for recovery of additional acrylic acid value from the organic phase.

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Patent Owner(s)

Patent OwnerAddress
THE DOW CHEMICAL COMPANY2030 DOW CENTER MIDLAND MI 48674

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Aguilo, Adolfo Corpus Christi, TX 8 485
Homer, Jr Cecil D Seabrook, TX 1 4
Smith, Brad L Portland, TX 21 877

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