Urethane elastomers prepared using a prepolymer prepared from a polyester which reacts with a chain-extending agent and/or a saturated polyester resin in which at least one of the polyesters is prepared from a dimer and/or trimer fatty acid
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United States of America Patent
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Jul 22, 1986
Grant Date -
N/A
app pub date -
Feb 21, 1985
filing date -
Feb 23, 1984
priority date (Note) -
Expired
status (Latency Note)
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Abstract
The hydrolysis resistance of a urethane elastomer prepared by reacting a hydroxy compound with a prepolymer in a weight ratio of between 5/95 and 95/5 is improved; the hydroxy compound consists of at least one saturated polyester resin and/or at least one chain-extending agent, if necessary in the presence of the usual additives, each resin and each chain-extending agent having at least two OH end groups; the prepolymer is prepared by reacting at least one saturated polyester resin having at least two OH end groups and at least one organic isocyanate of functionality .gtoreq.2, in molar excess. To this end, to prepare at least one polyester resin, a fraction of the polyacid(s) used is replaced by at least one polymerized fatty acid, consisting substantially of a dimer and/or a trimer, the initial total content of polymerized fatty acid(s) being between 1 and 35% by weight, referred to the finished product. The value of the load at break of the elastomer is retained to an extent of at least 50% or has a value at least equal to 5 MPa after hydrolysis.
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