Chromate composition and process for treating zinc-nickel alloys
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United States of America Patent
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May 27, 1986
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N/A
app pub date -
Jan 4, 1983
filing date -
Jan 4, 1983
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Expired
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Abstract
The present invention includes an aqueous acidic chromate solution, suitable for forming colored chromate coatings on zinc-nickel alloy electrodeposits containing up to about 15% by weight nickel, which solutions have a pH within the range of about 1.3 to about 2.7, a hexavalent chromium concentration of at least 0.5 grams per liter, and preferably about 0.5 to about 100 grams per liter, and which contain sulfate in a weight ratio of SO.sub.4 :Cr.sup.+6 of about 0.025-1.5:1. The zinc-nickel alloy electrodeposits are preferably immersed in the chromating solution for a period sufficient to form the desired colored chromate coating. In some instances, a flash electrodeposit of zinc may be applied to the zinc-nickel alloy electrodeposit before it is immersed in the chromating solution. Alternatively, the zinc-nickel alloy electrodeposit may be immersed in the chromating solution and the solution electrolyzed, with the zinc-nickel alloy surface as the anode, at low current densities for a short period of time, after which, the electrolysis is discontinued and the zinc-nickel alloy surface is maintained in the chromating solution until the desired colored chromate film is formed.
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