Method of making a catalytic lead-based oxygen evolving anode

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United States of America Patent

PATENT NO 4543174
SERIAL NO

06628533

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Abstract

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A method of making a catalytic lead-based oxygen-evolving anode comprises catalytically activating titanium sponge particles larger than 300 microns by impregnating with a solution containing Mn and Ru compounds, in amounts corresponding to Mn/Ru in an atomic ratio between 70/30 and 90/10, and thermally converting the compounds to an electrocatalyst comprising Mn and Ru in oxide form. Catalytic Ti sponge particles with up to 3 wt % Ru are thus produced, which are then uniformly distributed on the surface of a lead anode base in an amount greater than 400 g/m.sup.2, pressed, and partly embedded, thereby firmly anchoring and electrically connecting them to the lead anode base. The catalytic lead-based anode thus produced operates with oxygen evolution on the catalytic particles at a reduced potential at which the lead base remains electrochemically inactive. It thereby operates with significant energy savings over an extended service life.

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Patent Owner(s)

Patent OwnerAddress
ELECTRODE CORPORATION A CORP OF DE470 CENTER STREET CHARDON OH 44024

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Beer, Henri B Heide Kalmthout, BE 12 279
Hinden, Jean M Chambesy, CH 15 239
Katz, Michael Haifa, IL 162 2787

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