METHOD FOR DIRECTLY PREPARING TRIVALENT CHROMIUM COMPOUND BY ELECTROCHEMICAL OXIDATION OF FERROCHROME
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United States of America
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Apr 3, 2025
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Apr 23, 2023
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Apr 23, 2023
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Abstract
A method for directly preparing a trivalent chromium compound by electrochemical oxidation of ferrochrome is provided. The method includes: putting ferrochrome as an anode, and placing the anode into an electrolyte solution containing a complexing agent together with a cathode, then turning on a power supply for electrolysis reaction so that chromium and iron in ferrochrome are directly converted into free Cr3+ and Fe3+ respectively, allowing one of Cr3+ and fe3+ to form a stable soluble metal complex together with the complexing agent, and allowing the other of Cr3+ and Fe3+ to form a metal hydroxide solid together with OH− generated by electrolysis reaction, so as to obtain an electrolysis completion slurry. Compared with the prior art, the present application has no hexavalent chromium salt stage, thereby shortening the process flow and avoiding the generation of chromium-containing waste residue.
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