PHOTOCATALYTIC AEROBIC OXIDATION OF YPERITE OR AN ANALOG THEREOF

Number of patents in Portfolio can not be more than 2000

United States of America

APP PUB NO 20240390851A1
SERIAL NO

18692624

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Abstract

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The present invention relates to method for converting a sulfide of the following formula (I), such as yperite: R1—S—R2 (I) wherein R1 and R2, identical or different, are a (C1-C3)alkyl, (C2-C3)alkenyl, aryl, aryl-(C1-C3)alkyl, or aryl-(C2-C3)alkenyl group, said group being optionally substituted by one or several groups selected from a halogen atom, OR3, and NR4R5, and R3, R4, and R5 are, independently of one another, H or a (C1-C3)alkyl; into a sulfoxide of the following formula (II): R1—SO—R2 (II) wherein R1 and R2, are as defined above, wherein said method comprises oxidizing the sulfide of formula (I) in the presence of a catalyst. under an atmosphere comprising dioxygen, and under white or blue light irradiation, wherein the catalyst has the following formula (I): wherein Ar1, Ar2, Ar3, and Ar4 are, independently of one another, an aryl group optionally substituted by one or several groups selected from halogen, a (C1-C3)alkyl, OR6, and NR7R8, and R6, R7, and R8 are, independently of one another, H or a (C1-C3)alkyl. The present invention relates also to an air-filtering device comprising a catalyst of formula (I).

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Patent Owner(s)

Patent OwnerAddress
COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES25 RUE LEBLANC BÂTIMENT "LE PONANT D" PARIS F-75015

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
DORIS, Eric GIF-SUR-YVETTE, FR 6 4
GRAVEL, Edmond GIF-SUR-YVETTE, FR 3 3
OHEIX, Emmanuel MULHOUSE, FR 1 0

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