GRAPHENE OXIDE (GO)-MODIFIED STYRENE-ACRYLIC PICKERING EMULSION AND COMPOSITE EMULSION, AND PREPARATION METHODS AND USE
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United States of America
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Issued Date -
Nov 21, 2024
app pub date -
Jan 19, 2022
filing date -
Jan 19, 2022
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Abstract
The present disclosure relates to the technical field of protective coatings, and provides a graphene oxide (GO)-modified styrene-acrylic Pickering emulsion and a composite emulsion, and preparation methods and use. In the present disclosure, GO is added during polymerization of a styrene-acrylic monomer, and the GO is attached to an interface of a styrene-acrylic core while forming the styrene-acrylic core; and the GO is “stitched” at the interface of the styrene-acrylic core by a silane coupling agent, thus giving the GO a better dispersion effect. After adding a shell phase emulsion, a part of the styrene-acrylic core that is not completely wrapped by a GO sheet may be grafted with a shell phase, and cross-linking between a core phase and the shell phase can further enhance a steric stability of the GO; and the GO can fully connect the styrene-acrylic core with a siloxane shell, improving the molecular configuration of a siloxane component. In the composite emulsion, GO has desirable dispersibility and is not easy to agglomerate, such that the composite emulsion has an excellent performance and can significantly improve the durability of a cement-based material.
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