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Abstract

A vibrational circular dichroism (VCD) spectroscopy method and apparatus that can significantly reduce the measurement time needed to acquire a differential absorption spectrum compared to known approaches. A dual-comb is generated by superimposing the outputs from two quantum cascade laser sources, thus providing a third comb interferogram with beat frequencies higher than the polarization modulation frequency. Consequently, for each of the left and right circularly polarized light, the measurement signal measures transmission through the sample across the full wavelength range of interest during each period of the polarization modulation. A complete vibrational spectrum is thus acquired in each modulation of a polarization modulator, instead of only acquiring data for a single wavelength during each modulation of the polarization, as in dispersive or tunable laser VCD, or only a single Fourier component of the spectrum, as in Fourier transform VCD.

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