ALKALI METAL DOPED MOLYBDENUM CARBIDE SUPPORTED ON GAMMA-ALUMINA FOR SELECTIVE CO2 HYDROGENATION INTO CO
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Jun 7, 2017
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Jul 15, 2016
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Abstract
A class of catalysts for CO2 hydrogenation via the reverse water-gas shift (RWGS) reaction to selectively produce CO for down-stream hydrocarbon synthesis. Alkali metal-doped molybdenum carbide, supported on gamma alumina (A-Mo2C/γ-Al2O3, A=K, Na, Li), is synthesized by co-impregnation of molybdenum and alkali metal precursors onto a γ-Al2O3 support. The A-Mo/γ-Al2O3 catalyst is then carburized to form the A-Mo2C/γ-Al2O3. Also disclosed is the related method for CO2 hydrogenation via the RWGS reaction using the A-Mo2C/γ-Al2O3 catalyst.
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