SYNTHESIS OF R-GLUCOSIDES, SUGAR ALCOHOLS, REDUCED SUGAR ALCOHOLS, AND FURAN DERIVATIVES OF REDUCED SUGAR ALCOHOLS

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United States of America Patent

SERIAL NO

15302035

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Abstract

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Disclosed herein are methods for synthesizing 1,2,5,6-hexanetetrol (HTO), 1,6 hexanediol (HDO) and other reduced polyols from C5 and C6 sugar alcohols or R glycosides. The methods include contacting the sugar alcohol or R-glycoside with a copper catalyst, most desirably a Raney copper catalyst with hydrogen for a time, temperature and pressure sufficient to form reduced polyols having 2 to 3 fewer hydoxy groups than the starting material. When the starting compound is a C6 sugar alcohol such as sorbitol or R-glycoside of a C6 sugar such as methyl glucoside, the predominant product is HTO. The same catalyst can be used to further reduce the HTO to HDO.

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Patent Owner(s)

Patent OwnerAddress
ARCHER DANIELS MIDLAND COMPANY4666 FARIES PARKWAY DECATUR IL 62526

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
BINDER, Thomas P Decatur, US 50 581
SANBORN, Alexandra Lincoln, US 32 112

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