Process for the synthesis of a mixed peroxide or hydroxo-peroxide of an actinyl and of at least one doubly, triply or quadruply charged metal cation, mixed peroxide or hydroxo-peroxide thus obtained and uses thereof

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United States of America Patent

PATENT NO 10026510
APP PUB NO 20160314858A1
SERIAL NO

15104787

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Abstract

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A process is described for synthesizing a mixed peroxide or hydroxo-peroxide of an actinyl and at least one cation X1, wherein the actinyl is a uranyl or neptunyl and the at least one cation X1 is a di-, tri- or tetra-charged metal cation. This process includes the reaction in a solvent of a salt of the at least one cation X1 with a compound C2 selected from mixed peroxides and hydroxo-peroxides of the actinyl and of at least one singly charged cation X2, whereby compound C2 is converted to the peroxide or hydroxo-peroxide by replacement of the at least one cation X2 by said at least one cation X1. Also disclosed is a process for synthesizing a mixed oxide of an actinide selected from uranium and neptunium, and of at least one metal able to form a di-, tri- or tetra-charged cation, which implements the preceding synthesis process. The disclosure further relates to a mixed peroxide or hydroxo-peroxide of an actinyl and of at least one di-, tri- or tetra-charged metal cation, and the use thereof for the preparation of a mixed oxide of an actinide and of at least this metal.

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Patent Owner(s)

Patent OwnerAddress
ORANO RECYCLAGE125 AVENUE DE PARIS CHATILLON 92320

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Abraham, Francis Genech, FR 7 13
Blanchard, Florent Saint Barthelemy D'Anjou, FR 1 4
Grandjean, Stéphane Saint Marcel de Careiret, FR 2 6
Hablot, Isabelle Carriere sur Seine, FR 1 4
Rivenet, Murielle Baisieux, FR 4 6
Vigier, Nicolas Moret sur Loing, FR 6 27

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