METHOD FOR PRODUCING OPTICALLY ACTIVE 2,3-DIHYDROFARNESAL
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United States of America Patent
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Jan 29, 2016
filing date -
Sep 7, 2012
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Abstract
A method for producing an optically active 2,3-dihydrofarnesal of formula (1) is disclosed. The method includes subjecting β-farnesene f formula (2) to amination in the presence of a lithium salt of an amine to obtain (2E)-farnesyl allylamine of general formula (3); subjecting the (2E)-farnesyl allylamine to asymmetric isomerization to obtain an optically active farnesyl enamine of general formula (4); and subjecting the optically active farnesyl enamine to solvolysis:
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